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Palladium-catalyzed oxidative cyclization in alkaloid synthesis: total syntheses of (±)-cis- and trans-195A

✍ Scribed by Megumi Saeki; Masahiro Toyota

Publisher: Elsevier Science
Year: 2010
Tongue: French
Weight: 437 KB
Volume: 51
Category: Article
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2010.06.114

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✦ Synopsis

Total syntheses of (±)-cis-195A (1) and (±)-trans-195A ( ) have been accomplished by a combination of palladium-catalyzed oxidative cyclization and Beckmann rearrangement as key reactions.

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