𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Kinetic Control of Proline Amide Rotamers: Total Synthesis of trans,trans - and cis,cis -Ceratospongamide

✍ Scribed by Deng, Shaojiang; Taunton, Jack

Book ID
126149438
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
36 KB
Volume
124
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Cis-Trans equilibrium and kinetic studie
Cis-Trans equilibrium and kinetic studies of acetyl-L-proline and glycyl-L-proline
✍ H. N. Cheng; F. A. Bovey πŸ“‚ Article πŸ“… 1977 πŸ› Wiley (John Wiley & Sons) 🌐 English βš– 369 KB πŸ‘ 2 views

## Abstract By means of carbon‐13 nmr (at 25 MHz) the __trans/cis__ conformer ratio in glycyl‐L‐proline has been measured in aqueous (D~2~O) solution over the temperature range 33–96Β°C. It is found that Ξ”__H__^0^ = βˆ’4.2 kJ/mole and Ξ”__S__^0^ = βˆ’9.7 J/mole/K. Measurements of the __T__~1~ values for