Infrared photochemistry of bis(trifluoro
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J. S. Francisco; M. A. Findeis; J. I. Steinfeld
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Article
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1981
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John Wiley and Sons
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English
β 572 KB
Bis(trifluoromethy1) peroxide is readily dissociated by multiple infrared photon excitation at COz laser wavelengths. The primary dissociation product is CF30; approximately 85% of the nascent radicals are further dissociated in the laser field to form CFzO and F. The F atoms then react with the rem