𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The structures of dimethyl peroxide, CH3OOCH3, and bis-(trifluoromethyl) peroxide (CF3OOCF3)

✍ Scribed by William Gase; James E. Boggs


Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
237 KB
Volume
116
Category
Article
ISSN
0022-2860

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Ab initio study of some peroxides. HOOH,
✍ Dines Christen; Hans-Georg Mack; Heinz Oberhammer πŸ“‚ Article πŸ“… 1988 πŸ› Elsevier Science 🌐 French βš– 673 KB

The geometries of HOOH, CH300H, and CH300CH utro optimized with different basis sets (3-216. S-316 et4 ana 995\*') at different levels of theory (HF. HP2, fiP4, and CI). HF/3-2lC optirizations result in planar trans conformations for all three peroxides. HF/6-3lG\*+ calculations predict Skew conform

A reexamination of the pyrolysis of bis
✍ L. Batt; R. Walsh πŸ“‚ Article πŸ“… 1983 πŸ› John Wiley and Sons 🌐 English βš– 137 KB πŸ‘ 1 views

Earlier arguments concerning D(CF302-CF3) and D(CF3-02) are shown to be probably wrong. New values of 86 and 49 kcal/mol, respectively, are derived. C-0 bond strengths are compared between CF3-and CH3-containing compounds. This relation is of value only if D,(Oz) is independent of X. This is equival

Difluoromethylation of Amines with Zn(CF
✍ S. V. Pasenok; N. V. Kirij; Yu. L. Yagupolskii; D. Naumann; W. Tyrra; A. Fitzner πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 German βš– 93 KB πŸ‘ 1 views

The reactions of Zn(CF 3 )Br Β΄2 CH 3 CN, Cd(CF 3 ) 2 Β΄2 CH 3 CN or Bi(CF 3 ) 3 /AlCl 3 with tertiary amines lead to the formation of quaternary ammonium salts of the general formula [R 3 NCF 2 H]X. The reaction of 4-N,N-dimethylaminopyridine with Zn(CF 3 )Br Β΄2 CH 3 CN yields (Ndifluoromethyl)-4-N,N

Infrared photochemistry of bis(trifluoro
✍ J. S. Francisco; M. A. Findeis; J. I. Steinfeld πŸ“‚ Article πŸ“… 1981 πŸ› John Wiley and Sons 🌐 English βš– 572 KB

Bis(trifluoromethy1) peroxide is readily dissociated by multiple infrared photon excitation at COz laser wavelengths. The primary dissociation product is CF30; approximately 85% of the nascent radicals are further dissociated in the laser field to form CFzO and F. The F atoms then react with the rem