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A reexamination of the pyrolysis of bis trifluoromethyl peroxide. Addendum: Concerning D(CF3O2-CF3) and D(CF3-O2)

✍ Scribed by L. Batt; R. Walsh

Publisher: John Wiley and Sons
Year: 1983
Tongue: English
Weight: 137 KB
Volume: 15
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550150702

No coin nor oath required. For personal study only.

✦ Synopsis

Earlier arguments concerning D(CF302-CF3) and D(CF3-02) are shown to be probably wrong. New values of 86 and 49 kcal/mol, respectively, are derived. C-0 bond strengths are compared between CF3-and CH3-containing compounds. This relation is of value only if D,(Oz) is independent of X. This is equivalent tosaying that there is no special interaction between X and the unpaired electron in XO;. This is a reasonable presumption if X is a C-centered moiety, but is not likely to be true for electronegative substituents such as Fand C1-.

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