✦ LIBER ✦
Branching ratios for BrO production from reactions of O(1D) with HBr, CF3Br, CH3Br, CF2ClBr, and CF2HBr
✍ Scribed by J. M. Cronkhite; P. H. Wine
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 187 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0538-8066
No coin nor oath required. For personal study only.
✦ Synopsis
Laser-flash photolysis of RBr/O 3 /SF 6 /He mixtures at has been coupled with 248 nm BrO detection by time-resolved UV absorption spectroscopy to measure BrO product yields from O( 1 D) reactions with HBr, CF 3 Br, CH 3 Br, CF 2 ClBr, and CF 2 HBr at The measured 298 Ϯ 3 K. yields are: HBr, CF 3 Br, CH 3 Br, CF 2 ClBr, and 0.20 Ϯ 0.04; 0.49 Ϯ 0.07; 0.44 Ϯ 0.05; 0.31 Ϯ 0.06; CF 2 HBr, (uncertainties are 2 and include estimates of both random and system-0.39 Ϯ 0.07 atic errors). The results are discussed in light of other available information or 1 O( D) ϩ RBr reactions.