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Infrared photochemistry of bis(trifluoromethyl) peroxide

✍ Scribed by J. S. Francisco; M. A. Findeis; J. I. Steinfeld

Publisher: John Wiley and Sons
Year: 1981
Tongue: English
Weight: 572 KB
Volume: 13
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550130704

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✦ Synopsis

Bis(trifluoromethy1) peroxide is readily dissociated by multiple infrared photon excitation at COz laser wavelengths. The primary dissociation product is CF30; approximately 85% of the nascent radicals are further dissociated in the laser field to form CFzO and F. The F atoms then react with the remaining CF30 to produce CF30F. The formation of CF3OF is strongly inhibited by addition of HI, which reacts preferentially with the F atoms.

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