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A reexamination of the pyrolysis of bis trifluoromethyl peroxide

✍ Scribed by L. Batt; R. Walsh

Publisher: John Wiley and Sons
Year: 1982
Tongue: English
Weight: 595 KB
Volume: 14
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550140812

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✦ Synopsis

Abstract

The literature results for the pyrolysis of bis trifluoromethyl peroxide are reexamined and compared with those for dimethyl peroxide. The thermochemistry yields the result that the π‐bond energy in carbonyl fluoride is 96 ± 10 kcal/mol compared to 74 kcal/mol for that in formaldehyde. Thermodynamic additivity contributions are derived for the C(F)~3~(O) and O(C)(F) groups. Some conclusions are drawn in relation to the oxidation of halogeno methyl radicals and the chemistry of the atmosphere.

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