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Thianthrene 5-oxide as a probe of the electrophilicity of hemoprotein oxidizing species

✍ Scribed by Alvarez, Juan C.; Ortiz de Montellano, Paul R.

Book ID
126397679
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
994 KB
Volume
31
Category
Article
ISSN
0006-2960

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πŸ“œ SIMILAR VOLUMES

Thianthrene 5-Oxide as a Mechanistic Pro
Thianthrene 5-Oxide as a Mechanistic Probe in Oxygen Transfer Reactions: The Case of Carbonyl Oxides versus Dioxiranes Revisited
✍ Waldemar Adam; Dieter Golsch; Felix Christian GΓΆrth πŸ“‚ Article πŸ“… 1996 πŸ› John Wiley and Sons 🌐 English βš– 507 KB

Thianthrene 5-oxide (SSO) constitutes a useful mechanistic tool for the assessment of the electronic character of oxygen transfer agents by means of their X,, values, which reflect the extent of nucleophilic oxidation at the SO site in SSO. Treatment of dioxiranes 1 a-d with the SSO probe confirms t