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Application of the thianthrene 5-oxide mechanistic probe to peroxometal complexes

✍ Scribed by Ballistreri, Francesco P.; Tomaselli, Gaetano A.; Toscano, Rosa Maria; Conte, Valeria; Di Furia, Fulvio


Book ID
115505453
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
537 KB
Volume
113
Category
Article
ISSN
0002-7863

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Thianthrene 5-Oxide as a Mechanistic Pro
✍ Waldemar Adam; Dieter Golsch; Felix Christian GΓΆrth πŸ“‚ Article πŸ“… 1996 πŸ› John Wiley and Sons 🌐 English βš– 507 KB

Thianthrene 5-oxide (SSO) constitutes a useful mechanistic tool for the assessment of the electronic character of oxygen transfer agents by means of their X,, values, which reflect the extent of nucleophilic oxidation at the SO site in SSO. Treatment of dioxiranes 1 a-d with the SSO probe confirms t