Thianthrene 5-Oxide as a Mechanistic Pro
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Waldemar Adam; Dieter Golsch; Felix Christian GΓΆrth
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Article
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1996
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John Wiley and Sons
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English
β 507 KB
Thianthrene 5-oxide (SSO) constitutes a useful mechanistic tool for the assessment of the electronic character of oxygen transfer agents by means of their X,, values, which reflect the extent of nucleophilic oxidation at the SO site in SSO. Treatment of dioxiranes 1 a-d with the SSO probe confirms t