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ChemInform Abstract: Thianthrene 5-Oxide (I) as a Mechanistic Probe in Oxygen Transfer Reactions: The Case of Carbonyl Oxides versus Dioxiranes Revisited.

✍ Scribed by W. ADAM; D. GOLSCH; F. C. GOERTH


Book ID
112033726
Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
27
Category
Article
ISSN
0931-7597

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Thianthrene 5-Oxide as a Mechanistic Pro
✍ Waldemar Adam; Dieter Golsch; Felix Christian GΓΆrth πŸ“‚ Article πŸ“… 1996 πŸ› John Wiley and Sons 🌐 English βš– 507 KB

Thianthrene 5-oxide (SSO) constitutes a useful mechanistic tool for the assessment of the electronic character of oxygen transfer agents by means of their X,, values, which reflect the extent of nucleophilic oxidation at the SO site in SSO. Treatment of dioxiranes 1 a-d with the SSO probe confirms t