Probing for Electronic and Steric Effects in the Peracid Oxidation of Thianthrene 5-Oxide
β Scribed by Adam, Waldemar; Golsch, Dieter
- Book ID
- 125935743
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 147 KB
- Volume
- 62
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Thianthrene 5-oxide (SSO) constitutes a useful mechanistic tool for the assessment of the electronic character of oxygen transfer agents by means of their X,, values, which reflect the extent of nucleophilic oxidation at the SO site in SSO. Treatment of dioxiranes 1 a-d with the SSO probe confirms t
A study has been made of the oxidation of a number of substituted benzhydrols by chromic acid in aqueous acetic acid. The reaction rate constants are linearly proportional to the KR+ values of the alcohols. ortho-Substitution increases the rate of reaction and reduces the magnitude of the primary ki