The EPR spectra of bis(3quinolinethiohto)copper(II) and bis(SquinoIinoIato)copper(II) complexes arc re'corded both at 300 K and 7'7 K. The EPR parameters are obtained and the coefficients of the MO of the unpaired e!ectron are calculated. It is shown mat replacing of 0 atam with S cause a more str
Thermodynamic study and solvent effect of 8-quinolinethiolato complexes of manganese(II) and nickel(II) ions
β Scribed by Yasuo Nakabayashi; Yoshitaka Masuda
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 296 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0013-4686
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The overall stability constants of various metal &quinolinethiolato complexes ([M(c&]; M = Mn, Co, Ni, Cu, Zn, Cd, Hg) in DMSO have been obtained by a combination of the polarography of the sodium salt of I-quinolinethiol and the potentiometry with a mercury electrode based on the determination of t
## Abstract The first row transition metal ions Mn^2+^, Co^2+^, and Ni^2+^ have been studied by classical umbrella sampling molecular dynamics simulations. The water exchange mechanisms, estimates of reaction rates, as well as structural changes during the activation process are discussed. Mn^2+^ w