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Magnetic properties of binuclear manganese(II), cobalt(II), nickel(II) and copper(II) complexes of a macrocyclic ligand derived from pyridine-N-oxide, and crystal structure of the nickel complex

✍ Scribed by Antony B. Blake; Ekk Sinn; Ahmad Yavari; Boujemaa Moubaraki; Keith S. Murray


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
888 KB
Volume
229
Category
Article
ISSN
0020-1693

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Bis(terdentate) Pyrazole/Pyridine Ligand
✍ Akhilesh Kumar Singh; Jarl Ivar van der Vlugt; Serhiy Demeshko; Sebastian Decher πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 450 KB πŸ‘ 2 views

## Abstract A new binucleating bis(terdentate) ligand, 3,5‐[3‐bis(2‐pyridyl)pyrazole‐1‐ylmethyl]pyrazole (HL^2^), was synthesized. Reaction of the deprotonated ligand L^2^ with hydrated Cu^II^ salts gives (μ‐pyrazolato)(μ‐hydroxido)‐bridged binuclear and tetranuclear complexes [L^2^Cu~2~(μ‐OH)(ClO~