EPR study of bis(8-quinolinethiolato) copper(II) and bis(8-quinolinolato) copper(II) complexes
โ Scribed by N.D. Yordanov; M. Stankova; D. Shopov
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 246 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
โฆ Synopsis
The EPR spectra of bis(3quinolinethiohto)copper(II) and bis(SquinoIinoIato)copper(II)
complexes arc re'corded both at 300 K and 7'7 K. The EPR parameters are obtained and the coefficients of the MO of the unpaired e!ectron are calculated.
It is shown mat replacing of 0 atam with S cause a more strong delocalization of the unpaired electron on the figands.
๐ SIMILAR VOLUMES
Low temperature magnetic susceptibilit:r data for diacetyl-bis -(thiosemicarbazone)copper (II) have been interpreted in terms of the crystal structu!. e. There is an antiferromagnetic transition near 9%. The analysis of the EPR speckurn is consisient with the conclusions drawn from the susceptibilit
A single-crystal EPR sxdy of bis(O,O'di-iso-propyl-dithiophospharo) copper(U), [(~CJH,O)~PSSJICU, ma,onetically diluted in the corresponding Ni(I1) comples is repor!ed. The superhyperfine splitting from 31P nuclei of the l&ands is isotropic. The unpaired electron density on the dith.iophosphate liga