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EPR study of bis(8-quinolinethiolato) copper(II) and bis(8-quinolinolato) copper(II) complexes

โœ Scribed by N.D. Yordanov; M. Stankova; D. Shopov


Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
246 KB
Volume
39
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


The EPR spectra of bis(3quinolinethiohto)copper(II) and bis(SquinoIinoIato)copper(II)

complexes arc re'corded both at 300 K and 7'7 K. The EPR parameters are obtained and the coefficients of the MO of the unpaired e!ectron are calculated.

It is shown mat replacing of 0 atam with S cause a more strong delocalization of the unpaired electron on the figands.


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