✦ LIBER ✦

EPR studies of dithiophosphate and dithiocarbamate complexes. Single-crystal study of bis(O,O′-di-iso-propyl—dithiophosphato) copper(II)

✍ Scribed by N.D. Yordanov; D. Shopov

Publisher: Elsevier Science
Year: 1972
Tongue: English
Weight: 235 KB
Volume: 16
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(72)80458-5

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✦ Synopsis

A single-crystal EPR sxdy of bis(O,O'di-iso-propyl-dithiophospharo) copper(U), [(~CJH,O)~PSSJICU, ma,onetically diluted in the corresponding Ni(I1) comples is repor!ed. The superhyperfine splitting from 31P nuclei of the l&ands is isotropic. The unpaired electron density on the dith.iophosphate ligands is localised mainly on the sulphur atoms but no shfs from 33S is observed.