Low temperature magnetism and EPR of diacetyl-bis-(thiosemicarbazone) copper(II)
β Scribed by L.E. Warren; W.E. Hatfield
- Publisher
- Elsevier Science
- Year
- 1970
- Tongue
- English
- Weight
- 212 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
Low temperature magnetic susceptibilit:r data for diacetyl-bis -(thiosemicarbazone)copper (II) have been interpreted in terms of the crystal structu!. e. There is an antiferromagnetic transition near 9%. The analysis of the EPR speckurn is consisient with the conclusions drawn from the susceptibility measurements.
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The EPR spectra of bis(3quinolinethiohto)copper(II) and bis(SquinoIinoIato)copper(II) complexes arc re'corded both at 300 K and 7'7 K. The EPR parameters are obtained and the coefficients of the MO of the unpaired e!ectron are calculated. It is shown mat replacing of 0 atam with S cause a more str
A series of X-band electron paramagnetic resonance (EPR) spectra were obtained in the temperature range 120-280 K at 10 K intervals for the bis(acetylacetonate) complexes of copper(II) and oxovanadium(IV) cations in dimethylformamide. The magnetic parameters and molecular rotational correlation time