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Thermal substitution reactions of cupric benzoate IV

✍ Scribed by W. Schoo; J. U. Veenland; J. C. van Velzen; Th. J. de Boer; F. L. J. Sixma

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
250 KB
Volume
82
Category
Article
ISSN
0165-0513

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✦ Synopsis

Abstract

The reaction of cupric benzoate with carbon tetrachloride leads to the formation of a mixture of benzoyl chloride and ortho‐chlorobenzoyl chloride. On the basis of these data, the reactions of cupric benzoate are reconsidered. Most probably at about 200Β° the cupric benzoate forms a radical, stabilised by interaction of the cupric‐ion with the ortho position. With this stabilised radical all the reactions described in this and previous^1,2,3^ papers can be explained.

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