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Thermal substitution reactions of cupric benzoate II

✍ Scribed by W. Schoo; J. U. Veenland; Th. J. de Boer Boer; F. L. J. Sixma

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
157 KB
Volume
82
Category
Article
ISSN
0165-0513

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✦ Synopsis

Abstract

After thermal decomposition of cupric benzoate in the presence of deuterium oxide 43% of ortho‐deutero‐benzoic acid can be obtained beside phenol. A radical mechanism for the air oxidation of benzoic acid to phenol under the catalytic influence of copper oxide should therefore be reasonable.

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