Novel meso-substitution reactions of zinc(II) octaethylporphyrin
β Scribed by Brian Evans; Kevin M. Smith
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- French
- Weight
- 215 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
meso-Substituent effect on the redox properties of octaethylporphyrin and its zinc(lI) and copper(I1) complexes are investigated with cyclic volatmmetry. The El/2 values were observed to correlate linearly with Hammett's d, constant for the first and second oxidation reaction and the first reduction
On tb basis of polarographic studies and preparative investigationa at controlled anode potentials lr2, we have previously postulated that anodie acetorylation of an organic substrate in acetic acid/acetate Ion proceeddi via an initial two-electron transfer from the substrate to the anode. The dlcat
In the title mononuclear zinc(II) compound, [Zn(C 16 H 36 N 4 )]-(ClO 4 ) 2 , the Zn 2+ atom lies on an inversion center and is coordinated by four N atoms from the macrocyclic ligand. The coordination geometry is slightly distorted square planar.