## Abstract After thermal decomposition of cupric benzoate in the presence of deuterium oxide 43% of __ortho__โdeuteroโbenzoic acid can be obtained beside phenol. A radical mechanism for the air oxidation of benzoic acid to phenol under the catalytic influence of copper oxide should therefore be re
Thermal substitution reactions of cupric benzoate III
โ Scribed by W. Schoo; J. U. Veenland; Th. J. de Boer; F. L. J. Sixma
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 199 KB
- Volume
- 82
- Category
- Article
- ISSN
- 0165-0513
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โฆ Synopsis
Abstract
Among the reaction products of cupric benzoate and ammonia a small amount of aniline is found. Using [1โ^14^C]โbenzoic acid the position of the amino group is identified as ortho in relation to the original carboxyl group.
๐ SIMILAR VOLUMES
## Abstract The reaction of cupric benzoate with carbon tetrachloride leads to the formation of a mixture of benzoyl chloride and __ortho__โchlorobenzoyl chloride. On the basis of these data, the reactions of cupric benzoate are reconsidered. Most probably at about 200ยฐ the cupric benzoate forms a
## Abstract The thermal and the photochemical reactions of Co(CN)~5~H~2~O^2โ^ with azide, iodide, hydroazoic acid and hydrocyanic acid are investigated. Data on the photochemical aquation of Co(CN)^3โ^~6~ as a function of the chemical properties of the medium are also reported. On the basis of thes