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Reactions of excited molecules IV. Thermal isomerisation of the xylens.

✍ Scribed by W.D. Crow; C. Wentrup

Publisher
Elsevier Science
Year
1968
Tongue
French
Weight
227 KB
Volume
9
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES

Reactions of excited molecules v. Therma
Reactions of excited molecules v. Thermal decomposition of pyrazine
✍ W.D. Crow; C. Wentrup πŸ“‚ Article πŸ“… 1968 πŸ› Elsevier Science 🌐 French βš– 212 KB

In a previous publication (1) it was reported that pyrolysis of pyrazine-2,3-dicarboxylic anhydride led to the production of cis-and trans-dicyanoethylene, presumably through the intermediacy of 2,3\_dehydropyrazine.

Kinetics of the reactions of cyclopropan
Kinetics of the reactions of cyclopropane derivatives. IV. Kinetic isotope effect in the isomerisation of cyclopropylamine
✍ D. A. Luckraft; P. J. Robinson πŸ“‚ Article πŸ“… 1973 πŸ› John Wiley and Sons 🌐 English βš– 119 KB

## Abstract The high‐pressure isotopic rate ratio __k__~H~/__k__~D~ for isomerisation of cyclopropylamine and cyclopropylamine‐N‐__d__~2~ is 1.06 at 649–678 K, supporting a mechanism which does not involve migration of hydrogen from the amine group in the rate‐determining step.