Thermal rearrangement of cyclopropyl and alkenyl malonic esters

✍ Scribed by Wataru Ando

• Book ID: 104248561
• Publisher: Elsevier Science
• Year: 1969
• Tongue: French
• Weight: 143 KB
• Volume: 10
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(01)97701-9

✦ Synopsis

The thermal rearrangement of cyclopropyl ketones to homoallylic ketones is a efficient process which has recently become well docLmrented(l-3). We nowwishto report the thermal rearrangement of substituted cyclopropyl esters and to supply a new allylic transformation which occurs at higher temperature.