Thermal Rearrangement of {[2-(Arylmethylene)cyclopropyl]methyl}(phenyl)sulfanes and Selanes
β Scribed by Tian, Guo-Qiang; Li, Jia; Shi, Min
- Book ID
- 127340968
- Publisher
- American Chemical Society
- Year
- 2008
- Tongue
- English
- Weight
- 86 KB
- Volume
- 73
- Category
- Article
- ISSN
- 0022-3263
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## Abstract Bicyclo[2.1.0]pentβ5βyl methyl ketones undergo two thermal isomerization reactions. The __endoβexo__ stereomutation follows the ringβflip path in better than 90%, with inversion of the configuration of the angular carbon atoms by cleavage and reclosure of the central bond. Stereomutatio
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