3-Hydroperoxy-3-methyl-2-phenyl-3H-indole Thermal Decomposition and Chemiluminescence
✍ Scribed by Nakagawa, Masako; Sato, Masakazu; Watanabe, Yasiji; Hino, Tohru; Hatanaka, Yasumaru; Kanaoka, Yuichi
- Book ID
- 126702740
- Publisher
- Japan Institute of Heterocyclic Chemistry
- Year
- 1982
- Tongue
- English
- Weight
- 75 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0385-5414
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📜 SIMILAR VOLUMES
To a stirred solution of aluminium chloride (20 mmol) in dry tetrahydrofuran (100 ml), sodium azide (60 mmol) and 1-phenylsulfonyl-
In the title molecule, C 21 H 17 NO 3 S 2 , the sulfonyl-bound and sulfinyl-bound phenyl rings form dihedral angles of 82.04 (5) and 26.26 (8) , respectively, with the indole ring system. In the crystal structure C-HÁ Á ÁO, C-HÁ Á Á andinteractions form a two-dimensional network.
The phenyl ring in the title compound, C~15~H~11~Br~2~NO~2~S, makes a dihedral angle of 81.8 (1)° with the mean plane of the indole system. The molecular structure is stabilized by C—H...O hydrogen bonds.