Tetrachlorocyclopentadienylidene and Thermal Rearrangements of Its Cyclopropyl Adducts 1
โ Scribed by McBee, E. T.; Bosoms, J. A.; Morton, C. J.
- Book ID
- 126904682
- Publisher
- American Chemical Society
- Year
- 1966
- Tongue
- English
- Weight
- 765 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0022-3263
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๐ SIMILAR VOLUMES
The thermal rearrangement of cyclopropyl ketones to homoallylic ketones is a efficient process which has recently become well docLmrented(l-3). We nowwishto report the thermal rearrangement of substituted cyclopropyl esters and to supply a new allylic transformation which occurs at higher temperatur
Stereospecific 1,2-rearrangement of cyclopropyl group is described as an efficient route to stereo-defined a-cyclopropyl ketones and cr-cyclopropyl aldols. Acceleration of the reaction by the introduction of trimethylsilyl (TMS) group to the a-position of cyclopropyl group is also noted. ## Cyclop