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Multiple thermal rearrangements. II. Pyrolysis of alkenyl dihydrotropones

โœ Scribed by Cupas, Chris A.; Heyd, William E.; Kong, Ming-Sheng

Book ID
126057086
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
234 KB
Volume
93
Category
Article
ISSN
0002-7863

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## Abstract Flash vacuum pyrolysis of 1,2โ€dialkoxybenzenes 1aโ€c leads to the liberation of alkanes from the interacting side chains. A rearrangement of the skeleton yields the __o__โ€hydroxy carbonyl compounds 2 and 4. The generation of phenol 3 can be rationalized by a decarbonylation. The latter r