𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Multiple thermal rearrangements. Pyrolysis of 7-allyloxycycloheptatriene

✍ Scribed by Cupas, Chris A.; Schumann, William.; Heyd, William E.

Book ID
127344690
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
375 KB
Volume
92
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Multiple thermal rearrangements. III. Th
Multiple thermal rearrangements. III. The pyrolysis of 7-(3-butenyl)-cycloheptatriene
✍ C.A. Cupas; M.S. Kong; M. Mullins; W.E. Heyd πŸ“‚ Article πŸ“… 1971 πŸ› Elsevier Science 🌐 French βš– 154 KB

Nechanistic aspects of thermal sigmatropic rearrangements in cycloheptatrienes have been studied extensively.2 In contrast, the synthetic potential of these isomerization reactions has been exploited only recently. For example, a facile entry to tricyclo[4.3.1.03g8]decane (protoadamantane) derivativ

Multiple thermal rearrangements. : IV. T
Multiple thermal rearrangements. : IV. The pyrolysis of 2-(4-pentenyl)-dihydrotropone
✍ Leonard Hodakowski; Chris A. Cupas πŸ“‚ Article πŸ“… 1973 πŸ› Elsevier Science 🌐 French βš– 162 KB

In previous studies we have shown that the thermal rearrangement of appropriately substituded cycloheptatrienes and dihydrotropones provides a facile synthetic entry to new bridged polycyclic systems. For example, pyrolysis of 7-allyloxycycloheptatriene (lJ produces, in high yield, equal amounts of

Thermal rearrangements of 1,2-dialkoxybe
Thermal rearrangements of 1,2-dialkoxybenzenes by flash vacuum pyrolysis
✍ GrΓΆschl, Dieter ;Meier, Herbert πŸ“‚ Article πŸ“… 1995 πŸ› John Wiley and Sons 🌐 English βš– 133 KB

## Abstract Flash vacuum pyrolysis of 1,2‐dialkoxybenzenes 1a‐c leads to the liberation of alkanes from the interacting side chains. A rearrangement of the skeleton yields the __o__‐hydroxy carbonyl compounds 2 and 4. The generation of phenol 3 can be rationalized by a decarbonylation. The latter r