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ChemInform Abstract: Thermal Rearrangements of 1,2-Dialkoxybenzenes by Flash Vacuum Pyrolysis.

✍ Scribed by D. GROESCHL; H. MEIER


Book ID
112022308
Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
26
Category
Article
ISSN
0931-7597

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Thermal rearrangements of 1,2-dialkoxybe
✍ GrΓΆschl, Dieter ;Meier, Herbert πŸ“‚ Article πŸ“… 1995 πŸ› John Wiley and Sons 🌐 English βš– 133 KB

## Abstract Flash vacuum pyrolysis of 1,2‐dialkoxybenzenes 1a‐c leads to the liberation of alkanes from the interacting side chains. A rearrangement of the skeleton yields the __o__‐hydroxy carbonyl compounds 2 and 4. The generation of phenol 3 can be rationalized by a decarbonylation. The latter r