Thermal gas-phase reaction of perfluorobuta-1,3-diene with NO2
✍ Scribed by Joanna Czarnowski
- Book ID
- 108170522
- Publisher
- Elsevier Science
- Year
- 2008
- Tongue
- English
- Weight
- 189 KB
- Volume
- 129
- Category
- Article
- ISSN
- 0022-1139
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The kinetics of the gas phase reactions of NO, with a series of organics have been studied at 295 ? 2 K. It was observed that only 2,3-dimethyl-2-butene and the conjugated dialkenes studied reacted at observable rates, with rate constants which ranged from 1.5 x lo-" cm3 molecule-' s-' for 2,3-dimet
Structure-reactivity correlations are developed and used to test a biradical mechanism for gas-phase thermal Diels-Alder reactions of cyclohexa-1,3-diene with substituted ethenes and reverse reactions. 0 1994 John Wiley & Sons, Inc.
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