Selectivity-reactivity correlations are shown to support a biradical pathway for the gas phase thermal Diels-Alder reactions of cyclohexa-1,3-diene with substituted ethenes except for those involving a carbonyl group. \* All cycloadducts are considered as endo or ex0 according to the orientation of
Structure–reactivity correlations for gas-phase thermal Diels-Alder reactions of cyclohexa-1,3-diene with substituted ethenes and reverse reactions
✍ Scribed by G. Huybrechts; B. Van Mele
- Publisher
- John Wiley and Sons
- Year
- 1994
- Tongue
- English
- Weight
- 362 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0538-8066
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✦ Synopsis
Structure-reactivity correlations are developed and used to test a biradical mechanism for gas-phase thermal Diels-Alder reactions of cyclohexa-1,3-diene with substituted ethenes and reverse reactions. 0 1994 John Wiley & Sons, Inc.
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