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Selectivity–reactivity correlations for thermal Diels–Alder reactions of cyclohexa-1,3-diene with substituted Ethenes in the gas phase

✍ Scribed by B. Van Mele; G. Huybrechts

Publisher
John Wiley and Sons
Year
1989
Tongue
English
Weight
432 KB
Volume
21
Category
Article
ISSN
0538-8066

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✦ Synopsis

Selectivity-reactivity correlations are shown to support a biradical pathway for the gas phase thermal Diels-Alder reactions of cyclohexa-1,3-diene with substituted ethenes except for those involving a carbonyl group.

* All cycloadducts are considered as endo or ex0 according to the orientation of substituent Y '. For disubstituted dienophiles Y 1 must be the variable substituent and Y 2 , Y ' , or Y are always CH, groups.

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