✦ LIBER ✦

Gas phase reaction of NO2 with alkenes and dialkenes

✍ Scribed by Roger Atkinson; Sara M. Aschmann; Arthur M. Winer; James N. Pitts Jr.

Publisher: John Wiley and Sons
Year: 1984
Tongue: English
Weight: 412 KB
Volume: 16
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550160607

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✦ Synopsis

The kinetics of the gas phase reactions of NO, with a series of organics have been studied at 295 ? 2 K. It was observed that only 2,3-dimethyl-2-butene and the conjugated dialkenes studied reacted at observable rates, with rate constants which ranged from 1.5 x lo-" cm3 molecule-' s-' for 2,3-dimethyl-2-butene to 1.3 x lo-'' cm3 molecule-' s-' for a-phellandrene. These rate constants are compared with the available literature data and the mechanisms of these reactions are discussed.

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