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Thermal Decomposition of Cyclopentane-d 2 and Cyclopentane-Acetone-d 6 Mixtures. Reactions of the Allyl Radical

✍ Scribed by McNesby, James R.; Gordon, Alvin S.


Book ID
126100811
Publisher
American Chemical Society
Year
1957
Tongue
English
Weight
327 KB
Volume
79
Category
Article
ISSN
0002-7863

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Thermal reactions of ethane-d6–acetylene
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A study of the thermal decomposition of an acetylene-ethane-d6 mixture indicates that the rate constant for hydrogen abstraction from acetylene by methyl is more than 20 times less than for abstraction from ethane. Isotopic exchange is initiated by a rapid reaction between product D atoms and C2H2.