The Reaction of Methyl-d 3 Radicals with Cyclopropane and Cyclopentane
โ Scribed by McNesby, James R.; Gordon, Alvin S.
- Book ID
- 126957785
- Publisher
- American Chemical Society
- Year
- 1957
- Tongue
- English
- Weight
- 223 KB
- Volume
- 79
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
## Abstract The reaction of hydrogen atoms with diazomethane was used as a source of methyl radicals to study the reaction of oxygen atoms with methyl radicals. This investigation verifies directly the earlier results that formaldehyde is a major product and that the rate constant is greater than 3
The kinetics of reactions involving halogen atom abstraction from haloalkanes by methyl radicals have been studied in the gas phase. Arrhenius parameters for halogen atom transfer were determined relative to those for methyl radical combination: (2) ,,A2(L/rnol . s) E,(kcal/mol) CFC1, CF,CCl, CF,C