Kinetics and thermochemistry of the reaction C2D6 + Cl .dblharw. C2D5 + DCl. The heat of formation of the ethyl-d5 and ethyl radicals
β Scribed by Parmar, Sucha S.; Benson, Sidney W.
- Book ID
- 127328516
- Publisher
- American Chemical Society
- Year
- 1989
- Tongue
- English
- Weight
- 616 KB
- Volume
- 111
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
The initial rates of formation of the major products in the thermal reactions of ethylene at temperatures in the neighborhood of 800 K have been measured in the presence and absence of the additives neopentane and ethane. It has been shown that in the absence of the additive the main initiation proc
The gas-phase dehydrogenation of cyclopentene to cyclopentadiene catalyzed by iodine in. the range 178-283'C has been found to obey a rate law consistent with the slow rate-determining step, I + c-C5Hs --t HI + c-C5H, , log [ka/(l moleL1 sec-')I = 10.25 \* 0.08 -(12.26 f 0.18)/0, where 0 = 2.303RT i