Measurements and Modeling of DO 2 Formation in the Reactions of C 2 D 5 and C 3 D 7 Radicals with O 2†
✍ Scribed by Estupiñán, Edgar G.; Smith, Jared D.; Tezaki, Atsumu; Klippenstein, Stephen J.; Taatjes, Craig A.
- Book ID
- 126901623
- Publisher
- American Chemical Society
- Year
- 2007
- Tongue
- English
- Weight
- 414 KB
- Volume
- 111
- Category
- Article
- ISSN
- 1089-5639
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The rate coefficients for the gas-phase reactions of C,H,O;, and n-C3H,0, radicals with NO have been measured over the temperature range of (201 -403) K using chemical ionization mass spectrometric detection of the peroxy radical. The alkyl peroxy radicals were generated by reacting alkyl radicals w
The reaction of CF3 radicals with Ha0 (D20) has been studied over the range of 533-723 K using the photolysis and the pyrolysis of CFJ as the free radical source. Arrhenius pa- rameters for the reactions where X = H or D, relative to CF:j radical recombination are given by log kHlkf'2 = (5.12 f 0.1