Reactions of C 2 H 5 Radicals with O, O 3 , and NO 3 : Decomposition Pathways of the Intermediate C 2 H 5 O Radical
β Scribed by Hoyermann, K.; Olzmann, M.; Seeba, J.; Viskolcz, B.
- Book ID
- 126907026
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 83 KB
- Volume
- 103
- Category
- Article
- ISSN
- 1089-5639
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π SIMILAR VOLUMES
CzH50NO was photolyzed with 366 nm radiation at -48, -22, -2.5, 23, 55, 88, and 120Β°C in a static system in the presence of NO, 0,, and N,. The quantum yield of CH3CH0, (D{CH3CHO), was measured as a function of reaction conditions. The primary photochemical act is (la) CZHSONO + hv -\* CzH50 + NO an
The rate coefficients for the gas-phase reactions of C,H,O;, and n-C3H,0, radicals with NO have been measured over the temperature range of (201 -403) K using chemical ionization mass spectrometric detection of the peroxy radical. The alkyl peroxy radicals were generated by reacting alkyl radicals w