✦ LIBER ✦

Theoretical studies of reactions in a laser field: F(2P3/2, 2P1/2) + H2+ ħω (0.469 eV)

✍ Scribed by Isidore Last; Michael Baer; I.Harold Zimmerman; Thomas F. George

Publisher: Elsevier Science
Year: 1983
Tongue: English
Weight: 330 KB
Volume: 101
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(83)87363-1

No coin nor oath required. For personal study only.

✦ Synopsis

The collinear F(zPs/2, zPr$ + Ha system in a strong laser field is studied, employing the trajectory-surface-hopping method. The results are compared with a recent quanta1 study by Zimmerman, Baer and George. The two treatments yield low electronic non-adiabatic transition probabilities (~0.1). Good agreement is found in the high-energy region.

📜 SIMILAR VOLUMES

Quantal and semiclassical studies of the

Quantal and semiclassical studies of the (CO2) laser-induced reaction: F(2P1/2) + H2 → [F(2P3/2) + H2; HF + H]

✍ Michael Baer; Isidore Last; Yaakov Shima 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 436 KB

In this work we studied the collinear F(\*P,$ + Hz system in a strong CO2 laser field. It was found that the tiajecror) surface hopping method (TSHM) yields entirely different results than the exact quantum-mechanical treatment. A curvecrossing model was devised to esplain the discrepancy.

Reactivities of spin-orbit states in Al(

Reactivities of spin-orbit states in Al(2P1 2,3 2) + O2(X3Σg−) → AlO(X 2Σ+) + O(3P0,1,2). A fluorescence imaging study

✍ Kuo-mei Chen; Chun-hwa Sung; Jia-lin Chang; Teng-hui Chung; Kuo-huei Lee 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 434 KB

A crossed beam chemical reaction, AI(2P1/2,3/2)+ O2(X 3~g )..., AIO(X 2~ +)+ O(3P0,1,2) was investigated by fluorescence imaging techniques. Multiplex detection of speeds and quantum states of both reactants and products has been implemented. The two spin-orbit states of AI atoms display distinctive

A crossed molecular beam study of the ch

A crossed molecular beam study of the chemiluminescent reaction Xe(3P2,0) + BrCN → Xe(1S0) + Br + CN(B2Σ+)

✍ R.J. Hennessy; Yoko Ono; J.P. Simons 📂 Article 📅 1980 🏛 Elsevier Science 🌐 English ⚖ 448 KB

The c~ern~~~r~i~c~ce~t intcr~ction of Xef3i' energies ranging up to 70 kJ mol" z,e) artd BrC'N 1x1s been studicd under crossed-beam conditiorls et collision . The CNfR \* X) horuscencc spectrum, the excitation function for its production and the tluorcscence pnlnrisationor rather its absence \_ IWJC

Investigation of the molecular chemilumi

Investigation of the molecular chemiluminescence SrCl(A2Π1/2,3/2, B2Σ+ → X2Σ+) and the atomic resonance fluorescence Sr(53P1 → 51S0) in the time-domain following the pulsed dye laser generation of Sr(53 PJ) in the presence of CH2Cl2

✍ S. Antrobus; D. Husain; Jie Lei; F. Castaño; M. N. Sanchez Rayo 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 996 KB

## Abstract Time‐resolved investigations of the atomic resonance fluorescence Sr(5^3^P~1~ → 5^1^S~0~) and the molecular chemiluminescence from SrCl(A^2^Π~1/2,3/2~, B^2^Σ^+^ → X^2^Σ^+^) are reported following the reaction of the electronically excited strontium atom, Sr(5s5p(^3^P~J~)), 1.807 eV abov

Triphospholes as 2e and 4e donors: Synth

Triphospholes as 2e and 4e donors: Synthesis and structural characterization of the 1,2,4-triphosphole complexes η1-trans-[PtCl2(PEt3)(P3C2Bu3.0.CO;2-H/asset/equation/tex2gif-stack-1.gif?v=1&t=h5m61cg7&s=fa3a6bf97af99c538117b88f2890f7c6562d34b9" class="inlineGraphic">CH(SiMe3)2] and η1-η1-trans-[PtCl2(PEt3)2}2(μ-P3C2Bu3.0.CO;2-H/asset/equation/tex2gif-stack-2.gif?v=1&t=h5m61cg7&s=7fb7c40667376fc773adea0fb5af23d3be67ce36" class="inlineGraphic">CH(SiMe3)2]

✍ Vinicius Caliman; Peter B. Hitchcock; J. F. Nixon 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 376 KB 👁 2 views

The first examples of g 1 -complexes of 1,2,4-triphospholes are reported in which the ring acts as a 2e and a 4e donor.

Syntheses and Structures of C-Monoamino-

Syntheses and Structures of C-Monoamino-P-ferriophosphaalkenes[(η5-C5Me5)(CO)2FeP=CR1(NR3.0.CO;2-6/asset/equation/tex2gif-stack-1.gif?v=1&t=h5lehpiu&s=ab1cef7d5696b315a822f8407071feb16d2c4cb5" class="inlineGraphic">)] (R1 = Ph, tBu, 3,4,5-(MeO)3C6H2;NR3.0.CO;2-6/asset/equation/tex2gif-stack-2.gif?v=1&t=h5lehpiu&s=2f12a99bda7953d0b3084c39432c3f70455d15f1" class="inlineGraphic"> = NMe2, Piperidino)

✍ Lothar Weber; Stefan Kleinebekel; Annette Rühlicke; Hans-Georg Stammler; Beate N 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 389 KB 👁 2 views