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Quantal and semiclassical studies of the (CO2) laser-induced reaction: F(2P1/2) + H2 → [F(2P3/2) + H2; HF + H]

✍ Scribed by Michael Baer; Isidore Last; Yaakov Shima

Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
436 KB
Volume
110
Category
Article
ISSN
0009-2614

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✦ Synopsis

In this work we studied the collinear F(*P,$ + Hz system in a strong CO2 laser field. It was found that the tiajecror) surface hopping method (TSHM) yields entirely different results than the exact quantum-mechanical treatment. A curvecrossing model was devised to esplain the discrepancy.

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