✦ LIBER ✦

A crossed molecular beam study of the chemiluminescent reaction Xe(3P2,0) + BrCN → Xe(1S0) + Br + CN(B2Σ+)

✍ Scribed by R.J. Hennessy; Yoko Ono; J.P. Simons

Publisher: Elsevier Science
Year: 1980
Tongue: English
Weight: 448 KB
Volume: 75
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(80)80461-1

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✦ Synopsis

The c~ern~~~r~i~c~ce~t intcr~ction of Xef3i' energies ranging up to 70 kJ mol" z,e) artd BrC'N 1x1s been studicd under crossed-beam conditiorls et collision . The CNfR * X) horuscencc spectrum, the excitation function for its production and the tluorcscence pnlnrisationor rather its absence _ IWJC been determined. 'Ilie results cnn be cxplaincd by a two-stage hilrpooning mechnism involving an inert-gas cyanide (Xe+CN')* intermediate but not by II "scnsitisation" mccll;lnism proceeding through efectrunic energy trimsfcr,

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