✦ LIBER ✦

The vibronic theory of magnetic vibrational circular dichroism spectra of metalloporphyrins

✍ Scribed by Marek Pawlikowski; O.Sonnich Mortensen

Publisher: Elsevier Science
Year: 1990
Tongue: English
Weight: 421 KB
Volume: 168
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(90)85119-w

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✦ Synopsis

A simple multistate theory of magnetic vibrational circular dichroism (MVCD) in molecules of D, and D, symmetry is presented and used to interpret the MVCD spectrum for the 1346 cm-' fundamental in coppertetraphenylporphyrins. The perils inherent in interpreting such spectra via a single-state theory are discussed in some detail.

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