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A theory of magnetic vibrational circular dichroism

โœ Scribed by Thomas H. Walnut


Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
445 KB
Volume
114
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


A theory of type B magnetic vibrational circular dichroism (MVCD) is developed and applied. The motion of the nuclei is treated classically and the momentum correlation between their motion and the electronic motion is treated explicitly.


๐Ÿ“œ SIMILAR VOLUMES


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The magnetic vibrational circular dichroism spectra of C6o fullerene in solution are presented for excitation of the 1430 and 1183 cm-l ttu-symmetry fundamental vibrations. These transitions give rise to A-term MVCD of opposite sign (A~/Do= -3.8 and l. 1 ร— 10-4, respectively) which are similar in ma

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Magnetic-lield-induced circular dichroism of the vq mode of methane at 0.5 cm-' resolution is reported. For the first five members of the R branch, A, /DO is approximately constant, averaging -4.8 x 1 Om4, which corresponds to an average g, of + 0.44. This agrees in sign with and is z 40% higher tha