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Magnetic vibrational circular dichroism of C60

✍ Scribed by Cheok N. Tam; Baoliang Wang; Timothy A. Keiderling; William G. Golden

Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
368 KB
Volume
198
Category
Article
ISSN
0009-2614

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✦ Synopsis

The magnetic vibrational circular dichroism spectra of C6o fullerene in solution are presented for excitation of the 1430 and 1183 cm-l ttu-symmetry fundamental vibrations. These transitions give rise to A-term MVCD of opposite sign (A~/Do= -3.8 and l. 1 Γ— 10-4, respectively) which are similar in magnitude to that of benzene. Using the MCD spectra for the two lowest-energy ~T~u electronic excitations of C6o, the single excited-state vibronic coupling model correctly predicts the sign of one of the MVCD bands but underestimates both magnitudes.

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