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Rotational—vibrational circular dichroism

✍ Scribed by P.L. Polavarapu


Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
462 KB
Volume
161
Category
Article
ISSN
0009-2614

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📜 SIMILAR VOLUMES


Direct measurement of the rotational g-v
✍ Cheok N. Tam; Timothy A. Keiderling 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 311 KB

The magnetic vibrational circular dichroism (MVCD) spectra of the v 4 + v 5 combination band of acetylene was measured. From the result for the P(J" = 1 ~ J' = 0) rotational transition, the g j-value in the ground vibrational state for C2H 2 was determined to be + 0.049 (+ 0.005). The sign of the g

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

Vibrational circular dichroism of propyl
✍ R.W. Kawiecki; F. Devlin; P.J. Stephens; R.D. Amos; N.C. Handy 📂 Article 📅 1988 🏛 Elsevier Science 🌐 English ⚖ 582 KB

Calculations of the vibrational circular dichroism (VCD) and absorption spectra of propylene oxide over the range 700-1600 cm-' are compared with experimental spectra. VCD spectra are calculated using Stephens' equation for vibrational rotational strengths in the distributed origin gauge. Atomic pol

Magnetic vibrational circular dichroism
✍ Cheok N. Tam; Baoliang Wang; Timothy A. Keiderling; William G. Golden 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 368 KB

The magnetic vibrational circular dichroism spectra of C6o fullerene in solution are presented for excitation of the 1430 and 1183 cm-l ttu-symmetry fundamental vibrations. These transitions give rise to A-term MVCD of opposite sign (A~/Do= -3.8 and l. 1 × 10-4, respectively) which are similar in ma

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A theory of type B magnetic vibrational circular dichroism (MVCD) is developed and applied. The motion of the nuclei is treated classically and the momentum correlation between their motion and the electronic motion is treated explicitly.