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Magnetic vibrational circular dichroism of tetraphenylporphine and metallotetraphenylporphyrins

✍ Scribed by Paul V. Croatto; Timothy A. Keiderling

Publisher: Elsevier Science
Year: 1988
Tongue: English
Weight: 500 KB
Volume: 144
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(88)87295-6

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✦ Synopsis

Magnetic vibrational circular dichroism spectra of the title compounds are presented for the mid-IR region. The metalloporphytin E. modes have larger A terms than seen previously by an order of magnitude and are 2-3 times larger than in tetraphenylporphine. Comparison to the vibronic model is made.

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