Time-resolved resonance fluorescence detection of atomic chlorine following 266-nm laser flash photolysis of ClZCO/RSR'/N2 mixtures has been employed to study the kinetics of C1 reactions with HzS(kl), CH3SH(kz), DzS(k3), and CDsSD(k4) as a function of temperature (193-431 K) and pressure (25-600 to
The vibrational spectra of CD3SH and CD3SD in various phases and of CH3SH and CH3SD in the torsion vibration region of the two solid phases
β Scribed by Hans Wolff; Jerzy Szydlowski
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 473 KB
- Volume
- 160
- Category
- Article
- ISSN
- 0022-2860
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π SIMILAR VOLUMES
The Ξ½ 5 fundamental (C-C stretching) of CH 3 CD 3 shows a resolved torsional structure, caused by perturbations due mainly to the linear dependence of the torsional potential barrier on the normal coordinate Q 5 . We were able to analyze this structure and to assign vibration-rotation transition wav
Non-exponential proton spin-lattice relasation has been observed in solid Cl-I&H3 and CHsCD;. Comparison with recent theoretic31 predictions indicates XI intermethyl cross-correlation effect in CH&HJ which operates inaddition to the more commonly observed intramethyl cross-correlation intelactions.