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Cross-correlation effects in the spin—lattice relaxation curves of solid CH3CH3 and CH3CD3

✍ Scribed by L.J. Burnett; B.H. Muller

Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
402 KB
Volume
18
Category
Article
ISSN
0009-2614

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✦ Synopsis

Non-exponential proton spin-lattice relasation has been observed in solid Cl-I&H3 and CHsCD;. Comparison with recent theoretic31 predictions indicates XI intermethyl cross-correlation effect in CH&HJ which operates inaddition to the more commonly observed intramethyl cross-correlation intelactions.

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Torsional Splitting in the ν5 Fundamenta
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The ν 5 fundamental (C-C stretching) of CH 3 CD 3 shows a resolved torsional structure, caused by perturbations due mainly to the linear dependence of the torsional potential barrier on the normal coordinate Q 5 . We were able to analyze this structure and to assign vibration-rotation transition wav