Infrared and raman spectra of the lattice vibrations of CH3Cl and CD3Cl
โ Scribed by O.S. Binbrek; A. Anderson
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 457 KB
- Volume
- 65
- Category
- Article
- ISSN
- 0009-2614
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๐ SIMILAR VOLUMES
The I3C shielding of the isotopomers CH,Cl, CH,DCl, CHD,Cl, and CD,C1 has been calculated for a range of temperatures from an self-consistent field (SCF) shielding surface computed by Buckingham and Olegario. It is found that each successive deuterium substitution increases the shielding by about 0.
The infrared fluorescence risetimes of the vs C-Cl stretching mode of CHsCl have been measured in CHsCl-raregas mixtures subsequent to laser pumping of the ve methyl deformation vibration with a Q-switched CO2 laser. The rate of rise of this fluorescence was found to be 80 f 8 msec-'/torr in pure CH